A novel meroterpenoid cabagranin D was isolated with related neolignans cabagranins A–C from the leaves of
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Piper cabagranum (Costa Rica). Cabagranins A–C represent the first examples of 3,3′-neolignans isolated from the plant genusPiper , and the meroterpenoid cabagranin D displays an unprecedented Diels–Alder conjugate of an unsubstituted phenylpropenone and α-phellandrene. Details of the full structural elucidation of these compounds and a discussion of their potential biosynthetic relationships are presented.Free, publicly-accessible full text available January 4, 2025 -
Richards, Lora A. ; Dyer, Lee A. ; Forister, Matthew L. ; Smilanich, Angela M. ; Dodson, Craig D. ; Leonard, Michael D. ; Jeffrey, Christopher S. ( , Proceedings of the National Academy of Sciences)
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Glassmire, Andrea E. ; Jeffrey, Christopher S. ; Forister, Matthew L. ; Parchman, Thomas L. ; Nice, Chris C. ; Jahner, Joshua P. ; Wilson, Joseph S. ; Walla, Thomas R. ; Richards, Lora A. ; Smilanich, Angela M. ; et al ( , New Phytologist)